2 (s) + 3.75O 2 (aq) + 3.5(H 2 O)(l) → Fe(OH) 3 (s) + 2H 2 SO 4 (aq) This is what would occur if it was localized only to the pyritic rock, or shale layers. Because of the carbonate layers in the Marcellus Formation, calcium carbonate is introduced and further reactions can occur. In this case, gypsum can be formed as follows (Martin, 2008 ...

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A multiscale conceptual model of shale's structure: Level 0 corresponds to the elementary layer of clay minerals at the nanometer scale; Level I is the micrometer and sub-micrometer scale of the organic matter and clay particles consisting of hundreds of 1:1 or 2:1 layers stacked together; Level II represents the porous clay/organic matrix and granular …

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then hand grinding two parallel faces with 400, 600, then 1,500 grit emery cloth. A Struers Labopol-5 polishing machine was then used with 6 lm diamond suspension polishing fluid, followed by 1 lm diamond suspension polishing fluid, and finally 40 nm colloidal silica suspension. 3.2 FIB–SEM and EDX methods

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Oil shale is known to contain large amount of SiO 2 and Al 2 O 3 with catalytic effects on the deoxygenation process which also enhance the cracking reaction during pyrolysis . Other trace metals in oil shale, such as Ti, Mn and Zn, have positive effects on the reduction of polycyclic aromatic hydrocarbons (PAHs) during pyrolysis [ 6, 7 ].

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In contrast, a TOC above 2% enables to classify Niobrara as a black shale, with TOC (ge) 2%. Grinding and polishing procedure. Grinding and polishing protocol is essential for accurate microscopic testing by yielding a surface roughness much lower than the maximum penetration depth . Organic-rich shale is difficult to prepare as they exhibit ...

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The oil shale was received as hard dark gray blocks, typically 10–20 cm long, and 10–20 cm wide, and several cm thick. They were crushed using a rock-grinding device in order to reduce their size. A particle size range of 500–2000 μm was selected, and large particles were ground and sieved again. This particle size range was retained for ...

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mobile shale grinding machine Shale Crushing Line | China First Engineering . Shale is a finegrained, clastic sedimentary rock composed of mud that is a mix of flakes of clay minerals and tiny fragments (siltsized particles) of other minerals, especially quartz and calcite.[1]

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Pecking and grinding of hard granite provided long-lasting tools and stone implements. In 2011, stone artifacts from 15,500 years ago were discovered in an archaeological dig near Austin, Texas -- "the oldest credible archaeological site in North America," according to archaeologist Michael R. Waters of Texas A&M University.

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The present invention discloses a bionic shale inhibitor, consisting of structural units denoted by formula (1) and structural units denoted by formula (2), wherein, the molar ratio of the structural units denoted by formula (1) to the structural units denoted by formula (2) is 0.2-6:1, and the weight-average molecular weight of the shale inhibitor is 800-4,000 g/mol.

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Abstract. The effects of CO 2 and CO 2-based fluids imbibition on the mechanical properties of shale are of great importance in Sc-CO 2 enhanced shale gas production and geological sequestration of CO 2 in shale gas reservoirs. To investigate the influence of sub-CO 2, Sc-CO 2, sub-CO 2 –water, Sc-CO 2 –water, sub-CO 2 –Nacl, and Sc-CO 2 –Nacl …

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The investigated shale material was taken from outcrops of the Longmaxi Formation in Pengshui County, Chongqing, Southwest China. The dry density of the tested outcrops is approximately 2.66 g/cm 3 25; the pore throat radius of the tested shale is 6–15 nm, and the porosity is 4.7–5.2% 26; the particle grain diameters are approximately 5–15 μm 27; and X-ray …

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respect to grind size of oil shale particles. The ash content of 20.48% at. <200 microns decreased to 16.82% at <100 m icrons. Further reduction of the. particle size increased the ash of the ...

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@article{osti_7307069, title = {Quantitative determination of dawsonite in Green River shale by powder-sample x-ray diffraction: effect of grinding}, author = {Zen, E and Hammerstrom, J G}, abstractNote = {Weighed mixtures of drawsonite + quartz and of dawsonite + quartz + shale were ground for preset lengths of time, after which the following ...

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Though mechanical grinding using a Wig-L-Bug with a metal vial is more efficient, we employed hand grinding using a pestle and a mortar because extensive grinding may cause polymorphic transformation or altera-tion of mineral composition. Vibrating a sample in a stainless steel Wig-L-Bug for more than 1 minute will cause dehydration of gypsum [15].

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Request PDF | Investigation on breakage behaviour of oil shale with high grinding resistance: A comparison between microwave and conventional thermal processing | …

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thin-sectioned (thickness, 20–25 mm). Hand specimens were slabbed with a rock saw and thensmoothed and polishedwith grinding wheelsof successively ˜ner grit sizes (60–1200). High-resolution images of polished slabs and thin sections were acquired by standard photography and witha˚atbed scanner (1200–2400 dpi resolution).

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Figure 2 - Examples of diamond grinding disks, thin and thick. ... Trim off any bulk excess (like in Fig. 4a) with a saw, preferably a rock saw but it could be done by hand. Then it's time to rough grind the sample while making it …

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Italo Danioni s.r.l. 524. Manufacturer: Italo Danioni s.r.l. 8" x 12.5" product inlet (air swept product flow and grind control) 6"Ø flanged product outlet 4"Ø port / air vent sleeve Cast iron housing Super-Rex style, carbon steel grinding wheel 17.5"Ø X 5.5' wide (4900RPM...

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